Staff profile

Research Interests

NMR in the solid-state can provide detailed information on structure and dynamics in solid materials. Our research combines the development and evaluation of new techniques with applications to particular chemical problems, bridging the connection between the worlds of method development and practical application. We have an excellent range of facilities, based around dedicated solid-state NMR spectrometers: a 500 MHz research instrument, supported by two 400 MHz systems in our Solid-State NMR Service. Research projects can be largely experimental, largely theoretical/computational, or, more typically, a mix of experiment and computation.

Developments in solid-state and liquid crystal NMR of small molecules

Advances in hardware and methodology allow many of the elegant techniques of solution-state NMR to be applied to solid samples. We collaborate with a number of pharmaceutical companies (past and present sponsors include AstraZeneca and GlaxoSmithKline) to develop experimental techniques suitable for the study of pharmaceutical systems e.g. improving the sensitivity of ¹⁵N NMR to allow drug molecules to be characterised in formulated products, or characterizing the hydrogen-bonding in different polymorphs of the same substance.

At a more fundamental level, we have long-standing interests in the study of condensed phases with relatively high mobility, such as plastic crystals and other soft solids. This allows to characterise subtle NMR phenomena that are difficult to identify in classic solid-state NMR (as illustrated for a urea inclusion compound).

 

Structure and dynamics in inorganic systems

We also apply solid-state NMR to study of inorganic / hybrid framework materials. Characterisation of the structure of these materials by (powder) diffraction techniques alone is difficult, but combining the local information on structure and dynamics from multi-nuclear NMR (e.g. ²H, ³¹P) with the long-range structural information from diffraction studies, provide a much fuller understanding of these complex materials. The example illustrates the use of ¹⁷O NMR to study the dynamics of oxygen motion in ZrW₂O₈: solid-state NMR is only technique that allows to both quantify the dynamics and identify its chemical nature. We are continue to explore how solid-state NMR, powder XRD and first principles calculations can be integrated to solve increasingly complex structural problems.

• Solid-state NMR (theory and applications)
• Dynamics in the Solid State
• NMR Crystallography

Chapter in book

• Hodgkinson, P. (2010). High-Resolution H-1 NMR Spectroscopy of Solids. In G. Webb (Ed.), ANNUAL REPORTS ON NMR SPECTROSCOPY, VOL 72 (185-223). https://doi.org/10.1016/b978-0-12-385857-3.00005-0

Journal Article

• Hitchings, T. J., Wickins, H. M., Burley, L. G., Capelli, S. C., Demmel, F., Phillips, A. E., Hodgkinson, P., & Saines, P. J. (online). Probing the Structure and Dynamics of the [ NH 4 ]M( HCO 2 ) 3 Ferroelectric Phases: Dielectric Relaxation through Orientational Disorder. Chinese Journal of Chemistry, https://doi.org/10.1002/cjoc.202401192
• Guest, J. L., Bourne, E. A., Screen, M. A., Wilson, M. R., Pham, T. N., & Hodgkinson, P. (online). The essential synergy of MD simulation and NMR in understanding amorphous drug forms. Faraday Discussions, https://doi.org/10.1039/d4fd00097h
• Hampson, M., Hodgkinson, P., Evans, J., Harris, R., King, I., Allen, S., & Fayon, F. (online). The nature of oxygen exchange in ZrW2O8 revealed by two-dimensional solid-state O-17 NMR. Chemical Communications, 392-393
• Erastova, V., Evans, I. R., Glossop, W. N., Guryel, S., Hodgkinson, P., Kerr, H. E., Oganesyan, V. S., Softley, L. K., Wickins, H. M., & Wilson, M. R. (2024). Unravelling Guest Dynamics in Crystalline Molecular Organics Using 2 H Solid-State NMR and Molecular Dynamics Simulation. Journal of the American Chemical Society, 146(27), 18360-18369. https://doi.org/10.1021/jacs.4c03246
• Sacchi, P., Wright, S. E., Neoptolemou, P., Lampronti, G. I., Rajagopalan, A. K., Kras, W., Evans, C. L., Hodgkinson, P., & Cruz-Cabeza, A. J. (2024). Crystal size, shape, and conformational changes drive both the disappearance and reappearance of ritonavir polymorphs in the mill. Proceedings of the National Academy of Sciences, 121(15), Article e2319127121. https://doi.org/10.1073/pnas.2319127121
• Sturniolo, S., Wickins, H. M., & Hodgkinson, P. (2023). Revisiting the Van Vleck second moment for characterizing molecular motion in organic solids. The Journal of Chemical Physics, 158(24), https://doi.org/10.1063/5.0151022
• Hitchings, T. J., Wickins, H. M., Peat, G. U. L., Hodgkinson, P., Srivastava, A. K., Lu, T., Liu, Y., Piltz, R. O., Demmel, F., Phillips, A. E., & Saines, P. J. (2023). A new avenue to relaxor-like ferroelectric behaviour found by probing the structure and dynamics of [NH3NH2]Mg(HCO2)3. Journal of Materials Chemistry C Materials for optical and electronic devices, 11(28), 9695-9706. https://doi.org/10.1039/d3tc00480e
• Maunder, J., Aguilar, J., Hodgkinson, P., & Cooper, S. (2022). Structured ternary fluids as nanocrystal incubators for enhanced crystallization control. Chemical Science, 13(44), 13132-13140. https://doi.org/10.1039/d2sc04413g
• Skotnicki, M., & Hodgkinson, P. (2022). Characterization of crystalline and amorphous forms of irbesartan by multi-nuclear solid-state NMR. Solid State Nuclear Magnetic Resonance, 118, https://doi.org/10.1016/j.ssnmr.2022.101783
• Berlie, A., Terry, I., Szablewski, M., Telling, M., Apperley, D., Hodgkinson, P., & Zeller, D. (2022). A study of the dynamics and structure of the dielectric anomaly within the molecular solid TEA(TCNQ)2. Physical Chemistry Chemical Physics, 24(12), 7481-7492. https://doi.org/10.1039/d2cp00142j
• Crespi, A. F., Sánchez, V. M., Vega, D., Pérez, A. L., Brondino, C. D., Linck, Y. G., Hodgkinson, P., Rodríguez-Castellón, E., & Lázaro-Martínez, J. M. (2021). Paramagnetic solid-state NMR assignment and novel chemical conversion of the aldehyde group to dihydrogen ortho ester and hemiacetal moieties in copper(ii)- and cobalt(ii)-pyridinecarboxaldehyde complexes. RSC Advances, 11(33), 20216-20231. https://doi.org/10.1039/d1ra02512k
• Mashhadi, S. M. A., Yufit, D., Liu, H., Hodgkinson, P., & Yunus, U. (2020). Synthesis and structural characterization of cocrystals of isoniazid and cinnamic acid derivatives. Journal of Molecular Structure, 1219, Article 128621. https://doi.org/10.1016/j.molstruc.2020.128621
• Hodgkinson, P. (2020). NMR Crystallography of Molecular Organics. Progress in Nuclear Magnetic Resonance Spectroscopy, 118-119, 10-53. https://doi.org/10.1016/j.pnmrs.2020.03.001
• Widdifield, C., Farrell, J., Cole, J., Howard, J., & Hodgkinson, P. (2020). Resolving Alternative Organic Crystal Structures using Density Functional Theory and NMR Chemical Shifts. Chemical Science, 11(11), 2987-2992. https://doi.org/10.1039/c9sc04964a
• Dracinsky, M., Vícha, J., Bártová, K., & Hodgkinson, P. (2020). Towards accurate predictions of proton NMR parameters in molecular solids. ChemPhysChem, 21(18), 2075-2083. https://doi.org/10.1002/cphc.202000629
• Bismillah, A., Sturala, J., Chapin, B., Yufit, D., Hodgkinson, P., & McGonigal, P. (2018). Shape-Selective Crystallisation of Fluxional Carbon Cages. Chemical Science, 9(46), 8631-8636. https://doi.org/10.1039/c8sc04303e
• Pohl, R., Socha, O., Slavíček, P., Šála, M., Hodgkinson, P., & Dračínský, M. (2018). Proton transfer in guanine–cytosine base pair analogues studied by NMR spectroscopy and PIMD simulations. Faraday Discussions, 212, 331-344. https://doi.org/10.1039/c8fd00070k
• Ashbrook, S. E., & Hodgkinson, P. (2018). Perspective: Current advances in solid-state NMR spectroscopy. The Journal of Chemical Physics, 149(4), Article 040901. https://doi.org/10.1063/1.5038547
• Tatton, A. S., Blade, H., Brown, S. P., Hodgkinson, P., Hughes, L. P., Lill, S. O. N., & Yates, J. R. (2018). Improving Confidence in Crystal Structure Solutions Using NMR Crystallography: The Case of β-Piroxicam. Crystal Growth and Design, 18(6), 3339-3351. https://doi.org/10.1021/acs.cgd.8b00022
• Socha, O., Hodgkinson, P., Widdifield, C. M., Yates, J. R., & Dračínský, M. (2017). Exploring Systematic Discrepancies in DFT Calculations of Chlorine Nuclear Quadrupole Couplings. The Journal of Physical Chemistry A, 121(21), 4103-4113. https://doi.org/10.1021/acs.jpca.7b02810
• Kerr, H., Softley, L., Suresh, K., Hodgkinson, P., & Evans, I. (2017). Structure and Physicochemical Characterization of a Naproxen-Picolinamide Cocrystal. Acta Crystallographica Section C: Structural Chemistry, C73(3), https://doi.org/10.1107/s2053229616011980
• Frantsuzov, I., Vasa, S. K., Ernst, M. E., Brown, S. P., Zorin, V., Kentgens, A. P., & Hodgkinson, P. (2017). Rationalising heteronuclear decoupling in refocussing applications of solid-state NMR. ChemPhysChem, 18(4), 394-405. https://doi.org/10.1002/cphc.201601003
• Kerr, H. E., Mason, H. E., Sparkes, H. A., & Hodgkinson, P. (2016). Testing the limits of NMR crystallography: the case of caffeine-citric acid hydrate. CrystEngComm, 18(35), 6700-6707. https://doi.org/10.1039/c6ce01453d
• Sturniolo, S., Green, T., Hanson, R., Zilka, M., Refson, K., Hodgkinson, P., Brown, S., & Yates, J. (2016). Visualization and processing of computed solid-state NMR parameters: MagresView and MagresPython. Solid State Nuclear Magnetic Resonance, 78, 64-70. https://doi.org/10.1016/j.ssnmr.2016.05.004
• Smith, K., Burbidge, A., Apperley, D. C., Hodgkinson, P., Markwell, F. A., Topgaard, D., & Hughes, E. (2016). Stray-field NMR diffusion q-space diffraction imaging of monodisperse coarsening foams. Journal of Colloid and Interface Science, 476, 20-28. https://doi.org/10.1016/j.jcis.2016.04.053
• Widdifield, C. M., Robson, H., & Hodgkinson, P. (2016). Furosemide’s One Little Hydrogen Atom: NMR Crystallography Structure Verification of Powdered Molecular Organics. Chemical Communications, 52(40), 6685-6688. https://doi.org/10.1039/c6cc02171a
• Dračínský, M., Bour, P., & Hodgkinson, P. (2016). Temperature Dependence of NMR Parameters Calculated from Path Integral Molecular Dynamics Simulations. Journal of Chemical Theory and Computation, 12(3), 968-973. https://doi.org/10.1021/acs.jctc.5b01131
• Abraham, A., Apperley, D., Byard, S., Ilott, A., Robbins, A., Zorin, V., Harris, R., & Hodgkinson, P. (2016). Characterising the role of water in sildenafil citrate by NMR crystallography. CrystEngComm, 18(6), 1054-1063. https://doi.org/10.1039/c5ce02234g
• Skotnicki, M., Apperley, D., Aguilar, J., Milanowski, B., Pyda, M., & Hodgkinson, P. (2016). Characterization of Two Distinct Amorphous Forms of Valsartan by Solid-State NMR. Molecular Pharmaceutics, 13(1), 211-222. https://doi.org/10.1021/acs.molpharmaceut.5b00646
• Dračínský, M., Čechová, L., Hodgkinson, P., Procházková, E., & Janeba, Z. (2015). Resonance-assisted stabilisation of hydrogen bonds probed by NMR spectroscopy and path integral molecular dynamics. Chemical Communications, 51(73), 13986-13989. https://doi.org/10.1039/c5cc05199a
• Kerr, H. E., Softley, L. K., Kuthuru, S., Nangia, A., Hodgkinson, P., & Evans, I. R. (2015). A furosemide – isonicotinamide cocrystal: An investigation of properties and extensive structural disorder. CrystEngComm, 17(35), 6707-6715. https://doi.org/10.1039/c5ce01183c
• Frantsuzov, I., Ernst, M., Brown, S. P., & Hodgkinson, P. (2015). Simulating spin dynamics in organic solids under heteronuclear decoupling. Solid State Nuclear Magnetic Resonance, 70, 28-37. https://doi.org/10.1016/j.ssnmr.2015.05.003
• Skotnicki, M., Aguilar, J. A., Pyda, M., & Hodgkinson, P. (2015). Bisoprolol and Bisoprolol-Valsartan Compatibility Studied by Differential Scanning Calorimetry, Nuclear Magnetic Resonance and X-Ray Powder Diffractometry. Pharmaceutical Research, 32(2), 414-429. https://doi.org/10.1007/s11095-014-1471-7
• Bērziņš, A., & Hodgkinson, P. (2015). Solid-state NMR and computational investigation of solvent molecule arrangement and dynamics in isostructural solvates of droperidol. Solid State Nuclear Magnetic Resonance, 65, 12-20. https://doi.org/10.1016/j.ssnmr.2014.09.001
• Dračínský, M., & Hodgkinson, P. (2015). Solid-state NMR studies of nucleic acid components. RSC Advances, 5(16), 12300-12310. https://doi.org/10.1039/c4ra14404j
• Dračínský, M., Šála, M., & Hodgkinson, P. (2014). Dynamics of water molecules and sodium ions in solid hydrates of nucleotides. CrystEngComm, 16(29), 6756-6764. https://doi.org/10.1039/c4ce00727a
• Dračínský, M., & Hodgkinson, P. (2014). Effects of Quantum Nuclear Delocalisation on NMR Parameters from Path Integral Molecular Dynamics. Chemistry - A European Journal, 20(8), 2201-2207. https://doi.org/10.1002/chem.201303496
• Dračínský, M., & Hodgkinson, P. (2013). A molecular dynamics study of the effects of fast molecular motions on solid-state NMR parameters. CrystEngComm, 15(43), 8705-8712. https://doi.org/10.1039/c3ce40612a
• Ilott, A. J., Palucha, S., Hodgkinson, P., & Wilson, M. R. (2013). Well-Tempered Metadynamics as a Tool for Characterizing Multi-Component, Crystalline Molecular Machines. Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), 117(40), 12286-12295. https://doi.org/10.1021/jp4045995
• Apperley, D., Markwell, A., Frantsuzov, I., Ilott, A., Harris, R., & Hodgkinson, P. (2013). NMR characterisation of dynamics in solvates and desolvates of formoterol fumarate. Physical Chemistry Chemical Physics, 15(17), 6422-6430. https://doi.org/10.1039/c3cp50180a
• Tatton, A., Frantsuzov, I., Brown, S., & Hodgkinson, P. (2012). Unexpected effects of third-order cross-terms in heteronuclear spin systems under simultaneous radio-frequency irradiation and magic-angle spinning NMR. The Journal of Chemical Physics, 136(8), Article 084503. https://doi.org/10.1063/1.3684879
• Kleeberg, C., Crawford, A. G., Batsanov, A. S., Hodgkinson, P., Apperley, D. C., Cheung, M. S., Lin, Z., & Marder, T. B. (2012). Spectroscopic and Structural Characterization of the CyNHC Adduct of B(2)pin(2) in Solution and in the Solid State. Journal of Organic Chemistry, 77(1), 785-789. https://doi.org/10.1021/jo202127c
• Byard, S., Abraham, A., Boulton, P. J., Harris, R. K., & Hodgkinson, P. (2012). A multi-technique approach to the study of structural stability and desolvation of two unusual channel hydrate solvates of finasteride. Journal of Pharmaceutical Sciences, 101(1), 176-186. https://doi.org/10.1002/jps.22740
• Apperley, D. C., Batsanov, A. S., Clark, S. J., Harris, R. K., Hodgkinson, P., & Jochym, D. B. (2012). Computation of magnetic shielding to simultaneously validate a crystal structure and assign a solid-state NMR spectrum. Journal of Molecular Structure, 1015, 192-201. https://doi.org/10.1016/j.molstruc.2011.10.024
• Ilott, A., Palucha, S., Batsanov, A., Harris, K., Hodgkinson, P., & Wilson, M. (2011). Structural Properties of Carboxylic Acid Dimers Confined within the Urea Tunnel Structure: An MD Simulation Study. Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), 115(12), https://doi.org/10.1021/jp110137h
• Barrow, N. S., Yates, J. R., Feller, S. A., Holland, D., Ashbrook, S. E., Hodgkinson, P., & Brown, S. P. (2011). Towards homonuclear J solid-state NMR correlation experiments for half-integer quadrupolar nuclei: experimental and simulated B-11 MAS spin-echo dephasing and calculated (2)J(BB) coupling constants for lithium diborate. Physical Chemistry Chemical Physics, 13(13), 5778-5789. https://doi.org/10.1039/c0cp02343d
• Harris, R. K., Hodgkinson, P., Zorin, V., Dumez, J.-N., Elena-Herrmann, B., Emsley, L., Salager, E., & Stein, R. S. (2010). Computation and NMR crystallography of terbutaline sulfate. Magnetic Resonance in Chemistry, 48(1), S103-S112. https://doi.org/10.1002/mrc.2636
• Ilott, A., Palucha, S., Batsanov, A., Wilson, M., & Hodgkinson, P. (2010). Elucidation of Structure and Dynamics in Solid Octafluoronaphthalene from Combined NMR, Diffraction, And Molecular Dynamics Studies. Journal of the American Chemical Society, 132(14), 5179-5185. https://doi.org/10.1021/ja910526z
• Lister, S., Soleilhavoup, A., Withers, R., Hodgkinson, P., & Evans, J. (2010). Structures and Phase Transitions in (MoO2)2P2O7. Inorganic Chemistry, 49(5), 2290-2301. https://doi.org/10.1021/ic902166j
• Scholz, I., Hodgkinson, P., Meier, B., & Ernst, M. (2009). Understanding two-pulse phase-modulated decoupling in solid-state NMR. The Journal of Chemical Physics, 130(11), Article 114510. https://doi.org/10.1063/1.3086936
• Hogg, N., Boulton, P., Zorin, V., Harris, R., & Hodgkinson, P. (2009). Use of rotary echoes in 2H magic-angle spinning NMR for the quantitative study of molecular dynamics. Chemical Physics Letters, 475(1-3), 58-63. https://doi.org/10.1016/j.cplett.2009.05.031
• Zorin, V. E., Ernst, M., Brown, S. P., & Hodgkinson, P. (2008). Insights into homonuclear decoupling from efficient numerical simulation: Techniques and examples. Journal of Magnetic Resonance, 192(2), 183-196. https://doi.org/10.1016/j.jmr.2008.02.012
• Othman, A., Harris, R. K., Hodgkinson, P., Christopher, E. A., & Lancaster, R. W. (2008). Structural characterisation of two pharmaceutically important steroids by solid-state NMR. New Journal of Chemistry, 32(10), 1796-1806. https://doi.org/10.1039/b803586e
• Harris, R., Hodgkingson, P., Larsson, T., Muruganantham, A., Ymen, I., Yufit, D., & Zorin, V. (2008). Characterization of Polymorphs and Solvates of Terbutaline Sulfate. Crystal Growth and Design, 8(1), 80-90. https://doi.org/10.1021/cg700840j
• Zorin, V. E., Elena, B., Lesage, A., Emsley, L., & Hodgkinson, P. (2007). On the orientational dependence of resolution in H-1 solid-state NMR, and its role in MAS, CRAMPS and delayed-acquisition experiments. Magnetic Resonance in Chemistry, 45(S), S93-S100. https://doi.org/10.1002/mrc.2108
• Soleilhavoup, A., Hampson, M. R., Clark, S. J., Evans, J. S., & Hodgkinson, P. (2007). Using O-17 solid-state NMR and first principles calculation to characterise structure and dynamics in inorganic framework materials. Magnetic Resonance in Chemistry, 45(S), S144-S155. https://doi.org/10.1002/mrc.2128
• Harris, R. K., Hodgkinson, P., Pickard, C. J., Yates, J. R., & Zorin, V. (2007). Chemical shift computations on a crystallographic basis: some reflections and comments. Magnetic Resonance in Chemistry, 45(S), S174-S186. https://doi.org/10.1002/mrc.2132
• Othman, A., Evans, J. S., Evans, I. R., Harris, R. K., & Hodgkinson, P. (2007). Structural study of polymorphs and solvates of finasteride. Journal of Pharmaceutical Sciences, 96(5), 1380-1397. https://doi.org/10.1002/jps.20940
• Pham, T. N., Griffin, J. M., Masiero, S., Lena, S., Gottarelli, G., Hodgkinson, P., Fillip, C., & Brown, S. P. (2007). Quantifying hydrogen-bonding strength: the measurement of (2h)J(NN) couplings in self-assembled guanosines by solid-state (15)N spin-echo MAS NMR. Physical Chemistry Chemical Physics, 9(26), 3416-3423. https://doi.org/10.1039/b703513f
• Robbins, A., Ng, W., Jochym, D., Keal, T., Clark, S., Tozer, D., & Hodgkinson, P. (2007). Combining insights from solid-state NMR and first principles calculation: applications to the ¹⁹F NMR of octafluoronaphthalene. Physical Chemistry Chemical Physics, 9(19), 2389-2396. https://doi.org/10.1039/b701291h
• Zorin, V., Brown, S., & Hodgkinson, P. (2006). Origins of linewidth in ¹H magic-angle spinning NMR. The Journal of Chemical Physics, 125(14), https://doi.org/10.1063/1.2357602
• Hodgkinson, P., & Hampson, M. (2006). Quantitative analysis of 17O exchange and T1 relaxation data : Application to zirconium tungstate. Solid State Nuclear Magnetic Resonance, 30(2), 98-105. https://doi.org/10.1016/j.ssnmr.2006.04.001
• Zorin, V., Brown, S., & Hodgkinson, P. (2006). Quantification of homonuclear dipolar coupling networks from magic-angle spinning 1H NMR. Molecular Physics, 104(2), 293-304. https://doi.org/10.1080/00268970500351052
• Hampson, M., Evans, J., & Hodgkinson, P. (2005). Characterization of oxygen dynamics in ZrW₂O₈. Journal of the American Chemical Society, 127(43), 15175-15181. https://doi.org/10.1021/ja054063z
• Apperley, D. C., Forster, A. H., Fournier, R., Harris, R. K., Hodgkinson, P., Lancaster, R. W., & Rades, T. (2005). Characterisation of indomethacin and nifedipine using variable-temperature solid-state NMR. Magnetic Resonance in Chemistry, 43(11), 881-892. https://doi.org/10.1002/mrc.1643
• Hodgkinson, P. (2005). Heteronuclear decoupling in the NMR of solids. Progress in Nuclear Magnetic Resonance Spectroscopy, 46(4), 197-222. https://doi.org/10.1016/j.pnmrs.2005.04.002
• Harris, R., Hodgkinson, P., Larsson, T., & Muruganantham, A. (2005). Quantification of bambuterol hydrochloride in a formulated product using solid-state NMR. Journal of Pharmaceutical and Biomedical Analysis, 38(5), 858-864
• Hampson, M., Allen, S., King, I., Crossland, C., Hodgkinson, P., Harris, R., Fayon, F., & Evans, J. (2005). Synthesis and NMR studies of O-17 enriched AM(2)O(8) phases. Solid State Sciences, 7(7), 819-826
• Gobetto, R., Nervi, C., Chierotti, M., Braga, D., Maini, L., Grepioni, F., Harris, R., & Hodgkinson, P. (2005). Hydrogen bonding and dynamic behaviour in crystals and polymorphs of dicarboxylic-diamine adducts: A comparison between NMR parameters and X-ray diffraction studies. Chemistry - A European Journal, 11(24), 7461-7471. https://doi.org/10.1002/chem.200500616
• Amornsakchai, P., Apperley, D., Harris, R., Hodgkinson, P., & Waterfield, P. (2004). Solid-state NMR studies of some tin(II) compounds. Solid State Nuclear Magnetic Resonance, 26(3-4), 160-171
• Bowmaker, G., Harris, R., Assadollahzadeh, B., Apperley, D., Hodgkinson, P., & Amornsakchai, P. (2004). Solid-state Ag-109 CP/MAS NMR spectroscopy of some diammine silver(I) complexes. Magnetic Resonance in Chemistry, 42(9), 819-826
• Antonioli, G., & Hodgkinson, P. (2004). Resolution of C-13-F-19 interactions in the C-13 NMR of spinning solids and liquid crystals. Journal of Magnetic Resonance, 168(1), 124-131
• Amornsakchai, P., Hodgkinson, P., & Harris, R. (2004). NMR studies of P-31, H-1 spin pairs in solid tin(II) phosphite and tin(II) hydrogen phosphate. Molecular Physics, 102(9-10), 877-882
• De Paepe, G., Giraud, N., Lesage, A., Hodgkinson, P., Bockmann, A., & Emsley, L. (2003). Transverse dephasing optimized solid-state NMR spectroscopy. Journal of the American Chemical Society, 125(46), 13938-13939
• De Paepe, G., Hodgkinson, P., & Emsley, L. (2003). Improved heteronuclear decoupling schemes for solid-state magic angle spinning NMR by direct spectral optimization. Chemical Physics Letters, 376(3-4), 259-267
• McMillan, D., Hazendonk, P., & Hodgkinson, P. (2003). Interference of homonuclear decoupling and exchange in the solid-state NMR of perfluorocyclohexane. Journal of Magnetic Resonance, 161(2), 234-241
• De Paepe, G., Sakellariou, D., Hodgkinson, P., Hediger, S., & Emsley, L. (2003). Heteronuclear decoupling in NMR of Liquid Crystals using continuous phase modulation. Chemical Physics Letters, 368(5-6), 511-522
• Brauniger, T., Wormald, P., & Hodgkinson, P. (2002). Improved proton decoupling in NMR spectroscopy of crystalline solids using the SPINAL-64 sequence. Monatshefte für Chemie - Chemical Monthly, 133(12), 1549-1554
• Antonioli, G., McMillan, D., & Hodgkinson, P. (2001). Line-splitting and broadening effects from F-19 in the C-13 NMR of liquid crystals and solids. Chemical Physics Letters, 344(1-2), 68-74
• Hodgkinson, P., & Emsley, L. (2000). Numerical Simulation of Solid-State NMR Experiments
• Hodgkinson, P., Sakellariou, D., & Emsley, L. (2000). Simulation of Extended Periodic Systems of Nuclear Spins. Chemical Physics Letters, 326, 515-522